Hi Vicki:
Please contact your local La Leche League leader for specific advice regarding this...
Breastmilk itself is liquid, living tissue--full of all of those wonderful factors that make it the "magic elixer." The milk itself also contains digestive enzymes that in a sense help to pre-digest or aid in the digestive process (lactase to digest lactose, lipase to digest the fats).
Some women have high levels of lipase in their milk. When frozen/defrosted, the milk may have a soapy smell to it, and may seem unpalatable to you. It is not "bad", just a little pre-digested. Gently swirl the milk to mix it and see if the baby will take it (always handle milk like a fine wine... swirl, don't shake--shaking can jump-start the digestive process). Maybe use this milk to mix with cereals or thin purees?
There is a process of "scalding" milk that seems to reduce the "rancid" effect... I don't have my resource book with me right now to tell you how to do it... let me send this and see if I can cut and paste something...
Don't throw milk out unless absolutely necessary :-)!
From the La Leche Website:
Under most circumstances, fresh human milk has a mild, slightly sweet scent. Occasionally, human milk that has been frozen and thawed may smell soapy and may be rejected by the baby. In Breastfeeding: A Guide for the Medical Profession, Ruth Lawrence, MD, postulates that for some mothers, milk stored in a self- defrosting freezer may have had changes in its lipid structure due to the freeze-thaw cycles that occur in such freezers.
In a few cases, mothers have reported that their milk began to smell soapy as soon as it cooled, regardless of whether it had been frozen. "When these mothers heated their milk to a scald (not boiling) and then quickly cooled and froze it," writes Lawrence, "the effect was not apparent and their infants accepted the heat treated milk. That process inactivated the lipase (fat-digesting enzyme) and halted the process of fat digestion." However, high heating may lower some nutrient levels, including ascorbic acid (vitamin C). If the milk already smells sour, heating will have no effect on flavor or smell. Milk that smells rancid likely is, and should be discarded.